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This is a much harder recommendation than normal, because there are some big hurdles standing between the cards and the consumer

5 Celebi & Venusaur GX: The first card of the set gets this top slot

Currently, a single 12-pack collector booster box of Modern Horizons 2 will set you back somewhere between $390 and $425

But if your question is, What unofficial, licensed cards first had Pokemon on them? then sure, you can look at non-TCG products like Bandai Carddass

Love Ball (156/167) The Ultra Ball Trainer card is often thought of as one of the best Ball cards in the game, but this Love Ball card is arguably much more useful especially if you end up playing against an opponent who is using the same Pokemon as you